1. Digital Repository
  2. Science
  3. Chemistry
Please use this identifier to cite or link to this item: http://repository.kln.ac.lk/handle/123456789/3792
Title: Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne
Authors: Pandithavidana D R
Poloukhtine A
Popik V V
Issue Date: 2009
Publisher: Journal of the American Chemical Society
Abstract: Irradiation of the nine-membered ring enediyne precursor, which has one of its triple bonds masked as cyclopropenone, efficiently (? = 0.34) generates the reactive 4,5-benzocyclonona-2,6-diynol. The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstraction to produce the ultimate product of the Bergman cyclization, benz[f]indanol.
URI: http://repository.kln.ac.lk/handle/123456789/3792
Appears in Collections:Chemistry

Files in This Item:
There are no files associated with this item.
Show full item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.