Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne

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DC Field	Value	Language
dc.contributor.author	Pandithavidana D R	en_US
dc.contributor.author	Poloukhtine A	en_US
dc.contributor.author	Popik V V	en_US
dc.date.accessioned	2014-11-19T04:40:16Z	-
dc.date.available	2014-11-19T04:40:16Z	-
dc.date.issued	2009	-
dc.identifier.uri	http://repository.kln.ac.lk/handle/123456789/3792	-
dc.description.abstract	Irradiation of the nine-membered ring enediyne precursor, which has one of its triple bonds masked as cyclopropenone, efficiently (? = 0.34) generates the reactive 4,5-benzocyclonona-2,6-diynol. The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstraction to produce the ultimate product of the Bergman cyclization, benz[f]indanol.	en_US
dc.publisher	Journal of the American Chemical Society	en_US
dc.title	Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne	-
dc.type	article	en_US
dc.identifier.department	Chemistry	en_US
Appears in Collections:	Chemistry

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