Photochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne

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dc.contributor.authorPandithavidana D Ren_US
dc.contributor.authorPoloukhtine Aen_US
dc.contributor.authorPopik V Ven_US
dc.date.accessioned2014-11-19T04:40:16Z
dc.date.available2014-11-19T04:40:16Z
dc.date.issued2009
dc.description.abstractIrradiation of the nine-membered ring enediyne precursor, which has one of its triple bonds masked as cyclopropenone, efficiently (? = 0.34) generates the reactive 4,5-benzocyclonona-2,6-diynol. The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstraction to produce the ultimate product of the Bergman cyclization, benz[f]indanol.en_US
dc.identifier.departmentChemistryen_US
dc.identifier.urihttp://repository.kln.ac.lk/handle/123456789/3792
dc.publisherJournal of the American Chemical Societyen_US
dc.titlePhotochemical Generation and Reversible Cycloaromatization of a Nine-Membered Ring Cyclic Enediyne
dc.typearticleen_US

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