Fabrication and characterization of sulfur-treated cuprous oxide-based supercapacitors

Abstract

Supercapacitors are crucial for modern energy storage, offering high power density, fast charging, and life spans. They are widely used in various applications, meeting the need for lightweight, flexible, and eco-friendly energy solutions. Cuprous oxide (Cu2O) holds significant promise as an electrode material for supercapacitors owing to its distinctive properties. However, electrodeposited Cu2O films often have high resistivity and surface defects, hampering their electrochemical performance. To address this issue, sulfur treatment was employed to modify the surface properties of Cu2O electrodes, aiming to enhance their electrochemical performance. In this research, sulfur-treated Cuprous-oxide thin films were used as the supercapacitor electrodes, and PVA-KOH gel polymer was employed as the supercapacitor separator and electrolyte. The Cu2O films were synthesised on a Ti substrate via electrodeposition, followed by Ammonium Sulfide (NH4)2S vapour treatment for surface modification, with varying exposure times. Untreated Cu2O thin films were analysed for comparison. X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) were used to examine their structural and surface morphological characteristics. The XRD analysis showed that the Cu2O deposited on the Ti substrate treated with (NH4)2S vapour did not yield distinct CuxS peaks, indicating the formation of a very thin or amorphous CuxS layer on the film surface. SEM revealed an altered morphology of the electrodeposited Cu2O thin films after the (NH4)2S vapour treatment, with the development of a non-uniform additional layer on the surface. The electrochemical performance of sulfur-treated Cu2O electrodes for supercapacitors was studied using Cyclic Voltammetry (CV), Galvanostatic Charge/Discharge (GCD), and Electrochemical Impedance Spectroscopy (EIS). Sulfur-treated electrodes exhibited enhanced performance, showing higher specific capacitance, energy density, and power density compared to untreated electrodes. The supercapacitor utilising sulfur-treated Cu2O deposited on the Ti electrodes, treated for 10 s, demonstrated superior performance with a specific capacitance of 773.81 mF/g, energy density of 154.76 mWh/kg, and power density of 111.43 W/kg. Conversely, the untreated electrode-based supercapacitor exhibited lower values, with a specific capacitance of 23.34 mF/g, energy density of 4.67 mWh/kg, and power density of 3.38 W/kg. In summary, this study explored the impact of sulfur treatment on the electrochemical performance of electrodeposited Cu2O. CV, GCD, and EIS analyses revealed improved electrochemical performance due to the reduction of surface defects with (NH4)2S surface treatment. The results indicated that the best performance can be obtained in Cu2O with a 10 s (NH4)2S exposure duration for application in supercapacitors.