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Effect of thermal annealing of CBD-CdS on the electrical properties of CBD-CdS/ED-CdTe solar cell

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dc.contributor.author Gajanayake, G.K.U.P.
dc.contributor.author De Silva, D.S.M.
dc.contributor.author Atapattu, H.Y.R.
dc.contributor.author Thivakarasarma, T.
dc.date.accessioned 2021-01-25T10:26:17Z
dc.date.available 2021-01-25T10:26:17Z
dc.date.issued 2020
dc.identifier.citation Gajanayake, G.K.U.P., De Silva, D.S.M., Atapattu, H.Y.R. and Thivakarasarma, T. (2020). Effect of thermal annealing of CBD-CdS on the electrical properties of CBD-CdS/ED-CdTe solar cell. In : International Conference on Applied and Pure Sciences, 2020. Faculty of Science, University of Kelaniya, Sri Lanka, p.42. en_US
dc.identifier.uri http://repository.kln.ac.lk/handle/123456789/21822
dc.description.abstract Chemical bath deposition, Electrodeposition, Thermal annealing, CdS/CdTe solar cell Thermal annealing is one of the key steps to enhance the optoelectronic properties of the CdS/CdTe solar cells. In this study, the effects of annealing temperature and annealing time of chemical bath deposited (CBD) CdS on the electrical properties of CBD-CdS/electrodeposited (ED) CdTe solar cells were investigated. CBD-CdS layers were prepared using pre-optimized deposition conditions (90 ℃, 55 min) on fluorine doped tin oxide (FTO) glass substrates utilizing a bath consisted of 0.033 mol/L Cd(CH3COO)2, 0.667 mol/L CS(NH2)2 as cadmium and sulfur precursors, respectively and therein, 1 mol/L CH3CO2NH4 and 0.735 mol/L NH4OH were used for pH adjustment. Thereafter, a set of CBD-CdS samples prepared was annealed at different temperatures (350, 375 and 400 ℃) by varying the annealing time (10, 20, 30, and 40 min). Consequently, CdTe thin films were electrodeposited on annealed CBD-CdS substrates using an ED-bath consisted of 1.0 mol/L CdSO4 and 1.0 mmol/L TeO2 at pH of 2.3, temperature of 65 ℃, and potential of -650 mV against a saturated calomel electrode. The prepared glass/FTO/CBDCdS/ED-CdTe samples were air annealed (400 ℃, 20 min) and Cu/Au back contacts were deposited using thermal evaporation technique. The electrical properties of the CBD-CdS samples were investigated by photo-electrochemical cell (PEC) study at the CBD-CdS/electrolyte junction. As per the PEC analysis, CBD-CdS sample annealed at 375 ℃, 30 min has shown the highest short circuit current density (Jsc) of 21.5 μA/cm2 , while the sample annealed at 400 ℃, 10 min shown the highest open circuit voltage (Voc) of 499 mV. The electrical properties of the CBD-CdS/ED-CdTe/Cu/Au devices were investigated under AM 1.5 light source and therein, CBD-CdS sample annealed at 375 ℃, 30 min scored the highest Jsc (14.12 mA/cm2 ) and the one annealed at 400 ℃, 10 min displayed the highest Voc (616 mV). Also, the device annealed at 375 ℃, 30 min showed the lowest series resistance (205 Ω) while the one annealed at 400 ℃, 10 min demonstrated the highest shunt resistance (1401 Ω). Accordingly, the 375 ℃, 30 min and 400 ℃, 10 min were found to be the effective conditions for annealing CBD-CdS that can result in materials with better electrical properties for CBDCdS/ED-CdTe/Cu/Au device fabrication. en_US
dc.publisher Faculty of Science, University of Kelaniya, Sri Lanka en_US
dc.subject Chemical bath deposition, Electrodeposition, Thermal annealing, CdS/CdTe solar cell en_US
dc.title Effect of thermal annealing of CBD-CdS on the electrical properties of CBD-CdS/ED-CdTe solar cell en_US


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