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Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation

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dc.contributor.author Hutchins, K.M.
dc.contributor.author Rupasinghe, T.P.
dc.contributor.author Ditzler, L.R.
dc.contributor.author Swenson, D.C.
dc.contributor.author Sander, J.R.G.
dc.contributor.author Baltrusaitis, J.
dc.contributor.author Tivanski, A.V.
dc.contributor.author MacGillivray, L.R.
dc.date.accessioned 2017-11-08T03:19:43Z
dc.date.available 2017-11-08T03:19:43Z
dc.date.issued 2014
dc.identifier.citation Hutchins, K.M., Rupasinghe, T.P., Ditzler, L.R., Swenson, D.C., Sander, J.R.G., Baltrusaitis, J., Tivanski, A.V., and MacGillivray, L.R., (2014). Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation, American Chemical Society. Vol 136 (19). 6778-6781. en_US
dc.identifier.uri http://repository.kln.ac.lk/handle/123456789/17955
dc.description.abstract Ag(I) is used to form a π-stacked metal–organic solid that exhibits remarkably high electrical conductivity. The solid undergoes a single-crystal-to-single-crystal [2+2] photodimerization to generate a 1D coordination polymer with over 40% higher conductivity. The Ag(I) complex represents the first example of an increase in conductivity resulting from a [2+2] photodimerization. Density of states calculations show a higher contribution from Ag(I) ions to the valence band in the photodimerized solid, supporting the increase in conductivity. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society. en_US
dc.title Nanocrystals of a Metal–Organic Complex Exhibit Remarkably High Conductivity that Increases in a Single-Crystal-to-Single-Crystal Transformation en_US
dc.type Article en_US


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