Browsing by Author "Udawatta, M. M."

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    Development of energy briquettes using Schleichera oleosa (Ceylon oak) wood, Oryza sativa (rice husk, rice straws and rice brain) and Saccharum officinarum (bagasse)
    (Faculty of Science, University of Kelaniya Sri Lanka, 2023) Dulanjana, K. D. A.; Udawatta, M. M.; Prasad, P. D. A.; Bodaragama, T. P.; De Silva, D. S. M.
    Fossil fuels and firewood are the primary household energy sources in Sri Lanka. However, due to the economic crisis and the increasing inflation, fossil fuels are no longer a preferable choice. The use of firewood also has limitations, such as household air pollution due to the accumulation of smoke and toxic compounds causing immediate health issues. One of the solutions to this problem is the use of charcoal energy briquettes. Charcoal energy briquettes are compressed blocks made from pyrolyzed biomass residues. Burning these briquettes as an energy source, minimizes household air pollution and is energy efficient and cost-effective. Sri Lanka, a tropical agricultural country with significant vegetation growth, has great potential for developing carbonized charcoal briquettes from biomass energy sources such as ceyloan oak, rice husk, rice straws, bagasse and rice brain. In this study, Schleichera oleosa wood (Ceylon Oak) was used as the main component of the briquettes, as it was known to have a high calorific value. Ceylon Oak is used in furniture manufacturing, producing a large amount of sawdust waste, and this sawdust could be efficiently utilized to produce briquettes. Further, rice husk, rice straws, and bagasse with high ash content were used as additives to increase the burning time of the briquettes. Rice brain was used as the binding agent. During the study, the mixing ratios of the raw materials, pressure, and moisture content were varied to enhance the efficiency of the briquettes. Biomasses were pyrolyzed (300 °C, 1 h) to produce biochar. Different biochar mixtures (particle size < 2 mm) were compressed under different pressures (10 kPa - 60 kPa) using a newly innovated compressing machine to produce briquettes (OD: 4.15 cm, Height: 3.34 ±0.48 cm). They were dried in an oven (50 ℃) by varying the drying time (48 h, 72 h, 86 h, and 110 h) to change the moisture content. For each briquette produced, proximate analyses were carried out by measuring moisture (2% - 75%), volatile matter (20% - 36%), ash (10% - 30%), and fixed carbon content (38% - 70%). Calorific values were estimated based on the proximate analyses. The calorific values measured were in the range of 19,340 kJ kg-1 – 27,983 kJ kg-1 . Cooking efficiencies calculated were in the range of 2.5 kJ kg-1 - 27 kJ kg-1 exhibiting the potential of using these briquettes as a household energy source. According to this study, Schleichera oleosa and rice brain mixture 3:1 (w/w) ratio, showed the highest heating value and the highest cooking efficiency. The addition of rice husk, rice straw, and bagasse reduced the cooking efficiency of the briquettes. This study can be further extended to optimize other parameters of the briquettes (size, moisture content, compressed pressure and mixing ratios) to further enhance the cooking efficiency and burning time.
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    Facile, green approach for aqueous methylene blue dye adsorption: Coconut vinegar treated Trema orientalis wood biochar
    (Environmental Engineering Research, 2022) Udawatta, M. M.; De Silva, R.; De Silva, D.
    Biochar is widely utilized in low-cost water treatment. However, chemicals used in most of the recorded activation techniques are corrosive, may cause secondary pollution, and not accessible by rural communities, reducing their value of being cost-effective. In this study, Trema orientalis wood biochar (WB) was successfully activated with natural coconut vinegar employing a facile technique to produce a green adsorbent for efficient aqueous methylene blue (MB) removal. Batch studies showed a three-fold higher MB adsorption capacity of coconut vinegar treated wood biochar (CVWB) compared to WB. Percentage removal ranged between 98-79% at lower dye concentrations (50-100 mg/L) and 79-48% at higher dye concentrations (100-300 mg/L). Isotherm data best fitted to the Freundlich model. Kinetic data fitted to both pseudo second order and intraparticle diffusion models, suggesting that the adsorption was governed by a pore filling mechanism with predominant electrostatic attractions, and the reaction rate was diffusion controlled. FTIR, XPS, and water contact angle measurements confirmed increased surface oxygenated groups of CVWB. XPS showed a three-fold increase in O/C atomic ratio. BET and AFM studies gave evidence to the increased porosity. Therefore, the enhanced MB adsorption capacity of CVWB was attributed to both the increased surface oxygenated functional groups and porosity.