Browsing by Author "Comini, Elisabetta"

Now showing 1 - 2 of 2

Enhancing the Photovoltaic Performance of Cd(1􀀀x)ZnxS Thin Films Using Seed Assistance and EDTA Treatment
(Faculty of Science, University of Kelaniya Sri Lanka, 2023) Kumarage, G. W. C.; Wijesundera, Ruwan P.; Comini, Elisabetta; Dassanayake, Buddhika S.
This research article provides a comprehensive investigation into the optoelectronic characteristics of three distinct types of cadmium sulfide (CdS) thin films, namely: (a) conventionally prepared CdS thin films using chemical bath deposition (CBD-CdS), (b) CdS thin films produced via chemical bath deposition with the inclusion of zinc (CBD-Cd(1􀀀x)ZnxS, x = 0.3), and (c) CdS thin films synthesized using a seed-assisted approach, treated with ethylenediaminetetraacetic acid (EDTA), and incorporating zinc (ED/CBD + EDTA-Cd(1􀀀x)ZnxS). The investigation reveals that the crystallite size of these thin films decreases upon the addition of EDTA to the reaction solution, leading to an increase in the inter-planar spacing and dislocation density. Furthermore, a blue shift in the transmittance edge of the ED/CBD + EDTA-Cd(1􀀀x)ZnxS samples compared to CBD-CdS implies modifications in the band gaps of the deposited films. The incorporation of Zn2+ into the reaction solution results in an increased band gap value of up to 2.42 eV. This suggests that Cd(1􀀀x)ZnxS thin films permit more efficient photon transmission compared to conventional CdS. Among the three types of films studied, ED/CBD + EDTA-Cd(1􀀀x)ZnxS exhibits the highest optical band gap of 2.50 eV. This increase in the optical band gap is attributed to the smaller crystallite size and the splitting of the tail levels from the band structure. Additionally, the increment in the optical band gap leads to reduced light absorption at longer wavelengths, thereby enhancing the electrical properties. Notably, ED/CBD + EDTA-Cd(1􀀀x)ZnxS thin films demonstrate improved photovoltaic performance in a photoelectrochemical (PEC) cell, characterized by enhanced open-circuit voltage (363 mV, VOC), short-circuit current (35.35 A, ISC), and flat-band voltage (􀀀692 mV, Vfb). These improvements are attributed to the better adhesion of CdS to the fluorine-doped tin oxide (FTO) substrate and improved inter-particle connectivity.
Nb2O5 Microcolumns for Ethanol Sensing
(2024) Kumarage, Gayan W. C.; Panamaldeniya, Shasika A.; Maraloiu, Valentin A.; Dassanayake, Buddhika S.; Gunawardhana, Nanda; Comini, Elisabetta
Pseudohexagonal Nb2O5 microcolumns spanning a size range of 50 to 610 nm were synthesized utilizing a cost-effective hydrothermal process (maintained at 180 ◦C for 30 min), followed by a subsequent calcination step at 500 ◦C for 3 h. Raman spectroscopy analysis unveiled three distinct reflection peaks at 220.04 cm−1, 602.01 cm−1, and 735.3 cm−1, indicative of the pseudohexagonal crystal lattice of Nb2O5. The HRTEM characterization confirmed the inter-lattice distance of 1.8 Å for the 110 plain and 3.17 Å for the 100 plain. The conductometry sensors were fabricated by drop-casting a dispersion of Nb2O5 microcolumns, in ethanol, on Pt electrodes. The fabricated sensors exhibited excellent selectivity in detecting C2H5OH (ΔG/G = 2.51 for 10 ppm C2H5OH) when compared to a variety of tested gases, including CO, CO2, NO2, H2, H2S, and C3H6O. The optimal operating temperature for this selective detection was determined to be 500 ◦C in a dry air environment. Moreover, the sensors demonstrated exceptional repeatability over the course of three testing cycles and displayed strong humidity resistance, even when exposed to 90% relative humidity. This excellent humidity resistance gas sensing property can be attributed to their nanoporous nature and elevated operating temperature.